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Gadolinium(III) nitrate
πŸ‘ Image
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.030.385 πŸ‘ Edit this at Wikidata
  • InChI=1S/Gd.3NO3/c;3*2-1(3)4/q+3;3*-1 πŸ‘ check
    Y
    Key: MWFSXYMZCVAQCC-UHFFFAOYSA-N πŸ‘ check
    Y
  • InChI=1/Gd.3NO3/c;3*2-1(3)4/q+3;3*-1
    Key: MWFSXYMZCVAQCC-UHFFFAOYAX
  • [Gd+3].O=[N+]([O-])[O-].[O-][N+]([O-])=O.[O-][N+]([O-])=O
Properties
Gd(NO3)3
Molar mass 343.26 g/mol
Appearance White crystalline solid
Density 2.3 g/cm3
Melting point 91 Β°C (196 Β°F; 364 K)
Soluble
Hazards
GHS labelling:[1]
πŸ‘ GHS03: Oxidizing
πŸ‘ GHS05: Corrosive
πŸ‘ GHS07: Exclamation mark
πŸ‘ GHS09: Environmental hazard
Danger
H272, H315, H318, H319, H335, H410
P210, P220, P261, P264, P264+P265, P271, P273, P280, P302+P352, P304+P340, P305+P351+P338, P305+P354+P338, P317, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P391, P403+P233, P405, P501
Safety data sheet (SDS) External MSDS
Except where otherwise noted, data are given for materials in their standard state (at 25 Β°C [77 Β°F], 100 kPa).
Chemical compound

Gadolinium(III) nitrate is an inorganic compound of gadolinium with the formula Gd(NO3)3. A hydrate with the formula [Gd(NO3)3(H2O)4]Β·2H2O exists.[2] This salt is used as a water-soluble neutron poison in nuclear reactors.[3] Gadolinium nitrate, like all nitrate salts, is an oxidizing agent.

Use

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Gadolinium nitrate was used at the Savannah River Site heavy water nuclear reactors and had to be separated from the heavy water for storage or reuse.[4][5] The Canadian CANDU reactor, a pressurized heavy water reactor, also uses gadolinium nitrate as a water-soluble neutron poison in heavy water.

Gadolinium nitrate is also used as a raw material in the production of other gadolinium compounds, for production of specialty glasses and ceramics and as a phosphor.

References

[edit]
  1. ^ PubChem. "Gadolinium trinitrate". pubchem.ncbi.nlm.nih.gov. Retrieved 2025-12-18.
  2. ^ Taha, Z. A.; Ajlouni, A.; Hijazi, A. K.; KΓΌhn, F. E.; Herdtweck, E. (2012-07-01). "Redetermination of [Gd(NO3)3(H2O)4]Β·2H2O". Acta Crystallographica Section E: Structure Reports Online. 68 (7): i56–i57. doi:10.1107/S1600536812028000. ISSN 1600-5368. PMC 3393141.
  3. ^ DOE Fundamentals Handbook: Nuclear Physics and Reactor Theory (PDF). U.S. Department of Energy. January 1993. p. 31. Archived from the original (PDF) on 2008-04-23. Retrieved 2007-09-26.
  4. ^ E. Wilde; C. Berry. "Novel Method for Removing Gadolinium from Used Heavy Water Reactor Moderator".
  5. ^ E.W. Wilde; M.B. Goli; C.J. Berry; J.W. Santo Domingo; H.L. Martin. "Novel Method for Removing Gadolinium from Used Heavy Water Reactor Moderator" (PDF).