Number of Dyck paths with a "small Capital N" (a rise then a fall then a rise) - this follows from the exercise on p. 238 of Stanley stating that Motzkin numbers equal to the ballot number without (1,-1,1). Since Ballot numbers are Catalan numbers, the result follows from the well-known bijection with Dyck paths.
a(n + 2) = p(n + 2) where p(x) is the unique degree-n polynomial such that p(k) = Catalan(k) for k = 1, 2, ..., n+1. - Michael Somos, Oct 07 2003
REFERENCES
R. P. Stanley, Enumerative Combinatorics, Cambridge, Vol. 2, 1999; cf. p. 238.