Largest coefficient in expansion of (1 + x + x^2 + ... + x^(n-1))^5 = ((1-x^n)/(1-x))^5, i.e., the coefficient of x^floor(5*(n-1)/2) and of x^ceiling(5*(n-1)/2); also number of compositions of floor(5*(n+1)/2) into exactly 5 positive integers each no more than n.
a(2)=10 since the compositions of floor(5*(2+1)/2) = 7 into exactly 5 positive integers each no more than 2 are: 1+1+1+2+2, 1+1+2+1+2, 1+1+2+2+1, 1+2+1+1+2, 1+2+1+2+1, 1+2+2+1+1, 2+1+1+1+2, 2+1+1+2+1, 2+1+2+1+1, 2+2+1+1+1.