The Gcc with Gmp program is at the bottom of the link. The link also has a PARI bisection algorithm which gives a very good approximation for the n-th prime number and the n-th twin prime number. For example the 10^10-th lower twin prime approximation is 6100475249386, this has a relative error of 0.000000698... from the actual a(10) above.
The (10^n)-th upper twin prime is given as a(n)+2 = (5,109,3823,79561, 1260991,18409201,252427603,...). - M. F. Hasler, Dec 06 2008