a(n) ~ c * d^n * n^(2*n + 1/2) / exp(2*n), where d = 16/Pi^2 = 1.621138938277404343102071411355642222469740394755... is the root of the equation tan(1/sqrt(d)) = Pi*sqrt(d)/4 and c = 1.75568815831... - Vaclav Kotesovec, Dec 21 2017, updated Mar 16 2024