Fractions begin with 0, 0, 1/4, 4/7, 23/28, 53/56, 87/88, 593/594, 5807/5808, 415267/415272, 8758459/8758464, 274431867/274431872, ...
For n = 1 or 2 the number of pieces is less than 3, so the probability is 0.
For n = 3, the stick is being broken into 3 pieces and the probability that they can form a triangle is 1/4, the solution to the classical broken stick problem (see, e.g., Gardner, 2001).