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⇱ Guanine: Mineral information, data and localities.


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Guanine

A valid IMA mineral species
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About GuanineHide

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Formula:
C5H5N5O
structural formula: NCHNHC2C(O)NHC(NH2)N
Colour:
white
Hardness:
1 - 2
Crystal System:
Monoclinic
Name:
Bodo Unger reported a new material that believed was xanthine in 1844. Einbrodt (1846) showed the identification was incorrect. Unger (1846) agreed, provided a full corrected description and named it guanine after the guano it was found in.
Aromatic heterocycle (an organic cyclic carbon compound with additional, non-carbon atom(s)); a nucleobase and an important constituent of both DNA and RNA.

Spacing change of guanine crystals in the skin of chameleons is responsible for their showcase colour change (Teyssier et al. 2015).


Unique IdentifiersHide

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Mindat ID:
1763
Long-form identifier:
mindat:1:1:1763:9

Similar NamesHide

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GuaniteA synonym of Struvite(NH4)Mg(PO4) · 6H2O

IMA Classification of GuanineHide

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Approved
IMA Formula:
C5H3(NH2)N4O
Approval year:
1973
First published:
1844
Approval history:
The compound was already found in guano on North Chinca Island, Chile, by Bodo Unger in 1846, but it was confirmed as a natural occurence in bat guano from Murra-el-clevyn Cave, Nullarbor Plain, Western Australia, in 1973.

Classification of GuanineHide

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10.CA.30

10 : ORGANIC COMPOUNDS
C : Miscellaneous Organic Minerals
A : Miscellaneous Organic Minerals
50.4.5.1

50 : ORGANIC COMPOUNDS
4 : Miscellaneous
32.12

32 : Hydrocarbons, Resins and other Organic Compounds

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
GniIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of GuanineHide

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Transparency:
Transparent, Translucent
Colour:
White
Streak:
White
Hardness:
1 - 2 on Mohs scale

Optical Data of GuanineHide

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Type:
Biaxial

Chemistry of GuanineHide

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Mindat Formula:
C5H5N5O

structural formula: NCHNHC2C(O)NHC(NH2)N
Element Weights:
Element% weight
N46.341 %
C39.737 %
O10.587 %
H3.335 %

Calculated from ideal end-member formula.

Crystallography of GuanineHide

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Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/b
Setting:
P21/c
Cell Parameters:
a = 16.510 Å, b = 11.277 Å, c = 3.645 Å
β = 98.84°
Ratio:
a:b:c = 1.464 : 1 : 0.323
Unit Cell V:
670.58 ų (Calculated from Unit Cell)
Z:
4
Comment:
Synthetic

Crystal StructureHide

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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0009419GuanineThewalt U, Bugg C E, Marsh R E (1971) The crystal structure of guanine monohydrate Acta Crystallographica B27 2358-2362👁 Image
1971synthetic0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:
d-spacingIntensity
7.9 Å(40)
6.32 Å(70b)
3.53 Å(50)
3.22 Å(100b)
2.63 Å(50)
2.00 Å(50)
1.80 Å(50)
Comments:
Synthetic. (ICDD 28-2012)

Geological EnvironmentHide

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Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 10a: Neoproterozoic oxygenation/terrestrial biosphere<0.6
52 : Guano- and urine-derived minerals<0.4

Type Occurrence of GuanineHide

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Synonyms of GuanineHide

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Other Language Names for GuanineHide

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German:Guanin

Related Minerals - Strunz-mindat GroupingHide

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10.CA.AllantoinC4H6N4O3Mon. 2/m : P21/b
10.CA.PabellóndepicaiteCu2+2(N3C2H2)2(NH3)2(NO3)Cl · 2H2OOrth. mmm(2/m2/m2/m) : Pnna
10.CA.BojariteCu3(N3C2H2)3(OH)Cl2 · 6H2OIso. m3m(4/m32/m)
10.CA.NatrosulfatoureaNa2(SO4)[CO(NH2)2]Orth. mmm(2/m2/m2/m) : Pbcn
10.CA.'Tholins'(C,H,N)
10.CA.FuchuniteBa(C2H3O3)2(C2H4O3)2Mon. 2/m : P21/b
10.CA.05RefikiteC20H32O2Orth. 222 : P21212
10.CA.10FlagstaffiteC10H22O3Orth. mm2 : Fdd2
10.CA.15HoeliteC14H8O2Mon. 2/m : P21/b
10.CA.20AbelsoniteNi(C31H32N4)Tric. 1 : P1
10.CA.25KladnoiteC6H4(CO)2NHMon. 2/m
10.CA.30'Tinnunculite (of Chesnokov & Shcherbakova)'C10H12N8O8Orth.
10.CA.35UreaCO(NH2)2Tet. 42m : P421m
10.CA.40UriciteC5H4N4O3Mon. 2/m : P21/b
10.CA.45ChanabayaiteCuCl(N3C2H2)(NH3) · 0.25H2OOrth. mmm(2/m2/m2/m) : Imma
10.CA.50TriazoliteNaCu2(N3C2H2)2(NH3)2Cl3 · 4H2OOrth. 222 : P212121
10.CA.55ErnstburkeiteMg(CH3SO3)2 · 12H2O Trig. 3 : R3
10.CA.60JoanneumiteCu(C3N3O3H2)2(NH3)2Tric. 1 : P1
10.CA.65TinnunculiteC5H4N4O3 · 2H2OMon. 2/m : P21/b
10.CA.70'Dopplerite'Amor.

Other InformationHide

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Notes:
M.P. 360 ◦C
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for GuanineHide

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References for GuanineHide

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Localities for GuanineHide

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Showing 8 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the 👁 Image
symbol to view information about a locality. The 👁 Image
symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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👁 Image
- This locality has map coordinates listed.
👁 Image
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. 👁 Image
- Good crystals or important locality for species.
👁 Image
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Australia
  • Western Australia
    • Dundas Shire
      • Cocklebiddy Roadhouse
Caves: processes +2 other references
      • Madura Roadhouse
Bridge (1977)
Chile
  • Antofagasta
    • El Loa Province
      • San Pedro de Atacama
        • Cordillera de la Sal
De Waele et al. (2009)
De Waele et al. (2017)
Mexico
  • Chihuahua
    • Saucillo Municipality
      • Naica
Gazquez et al. (1)
  • Coahuila
    • Cuatro Ciénegas Municipality
      • Cuatro Ciénegas (Cuatrociénegas de Carranza; Venustiano Carranza)
        • Limestone caves
Forti (2006)
Peru (TL)
  • Ica
    • Pisco Province
      • San Clemente District
        • Chincha Islands
Min Mag 39 (1974)
South Africa
  • Western Cape
    • West Coast District Municipality
Cairncross et al. (1995)
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