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⇱ Sayrite: Mineral information, data and localities.


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Sayrite

A valid IMA mineral species
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About SayriteHide

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Formula:
Pb2(UO2)5O6(OH)2 · 4H2O
structural formula: Pb2(H2[4]O)4[(UO2)5O6(OH)2
Colour:
Yellow-orange to red-orange
Lustre:
Adamantine, Vitreous
Specific Gravity:
6.76 (Calculated)
Crystal System:
Monoclinic
Name:
Named after David Sayre (2 March 1924, New York, New York, USA - 23 February 2012, Ashland, Oregon, USA), crystallographer, IBM Corporation, USA. The Sayre equation, used in crystallography, is named after him. He was also part of the initial team that created the FORTRAN programming language.
This page provides mineralogical data about Sayrite.


Unique IdentifiersHide

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Mindat ID:
3545
Long-form identifier:
mindat:1:1:3545:9

Similar NamesHide

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Cerite
Cerite-(CeCa)A valid IMA mineral species - grandfathered(Ce7Ca2)◻Mg(SiO4)3(SiO3OH)4(OH)3
Cerite-(La)A synonym of Ferricerite-(LaCa)(La6Ca3)◻Fe3+(SiO4)3(SiO3OH)4(OH)3
SuriteA valid IMA mineral species(Pb,Ca)3(Al,Fe2+,Mg)2((Si,Al)4O10)(CO3)2(OH)2
ZaïriteA valid IMA mineral speciesBiFe33+(PO4)2(OH)6
ZoriteA valid IMA mineral speciesNa8(Ti,Nb)5(Si6O17)2(OH,O)5 · 14H2O

IMA Classification of SayriteHide

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Classification of SayriteHide

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4.GB.50

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
G : Uranyl Hydroxides
B : With additional cations (K, Ca, Ba, Pb, etc.); with mainly UO2(O,OH)5 pentagonal polyhedra
5.9.6.1

5 : OXIDES CONTAINING URANIUM OR THORIUM
9 : Miscellaneous
7.16.30

7 : Oxides and Hydroxides
16 : Oxides of U

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
SyrIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Pronunciation of SayriteHide

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Pronunciation:
PlayRecorded byCountry
Jolyon RalphUnited Kingdom

Physical Properties of SayriteHide

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Adamantine, Vitreous
Transparency:
Transparent, Translucent
Colour:
Yellow-orange to red-orange
Hardness:
VHN100=150 - Vickers
Cleavage:
Distinct/Good
distinct {102}
Density:
6.76 g/cm3 (Calculated)

Optical Data of SayriteHide

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Type:
Biaxial (-)
Dispersion:
relatively weak
Pleochroism:
Visible
Comments:
Y pale yellow, Z amber
Comments:
Refractive index along α was not measurable
2V was 'large'
X ~ a, Y = b, Z ~ c

Chemistry of SayriteHide

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Mindat Formula:
Pb2(UO2)5O6(OH)2 · 4H2O

structural formula: Pb2(H2[4]O)4[(UO2)5O6(OH)2
Element Weights:
Element% weight
U60.518 %
Pb21.072 %
O17.898 %
H0.513 %

Calculated from ideal end-member formula.

Crystallography of SayriteHide

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Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Cell Parameters:
a = 10.6925(4) Å, b = 6.9593(2) Å, c = 13.6035(5) Å
β = 107.680(3)°
Ratio:
a:b:c = 1.536 : 1 : 1.955
Unit Cell V:
964.46 ų
Z:
2
Morphology:
Prismatic crystals elongated along b and flattened on {102}
Comment:
space group is P21/n

Crystal StructureHide

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Load
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2x2x2 | 3x3x3 | 4x4x4
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Big Balls | Small Balls | Just Balls | Spacefill
Polyhedra Off | Si Polyhedra | All Polyhedra
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0012080SayritePiret P, Deliens M, Piret-Meunier J, Germain G (1983) La sayrite, Pb2[(UO2)5O6(OH)2]*4H2O, nouveau mineral; proprietes et structure cristalline Bulletin de Mineralogie 106 299-3041983Shinkolobwe, Shaba, Zaire0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:
d-spacingIntensity
7.01 Å(80)
5.67 Å(50)
3.512 Å(90)
3.426 Å(40)
3.113 Å(100)
3.052 Å(70)
1.955 Å(50)

Geological EnvironmentHide

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Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 7: Great Oxidation Event<2.4
47a : [Near-surface hydration of prior minerals]
47f : [Uranyl (U⁶⁺) minerals]

Type Occurrence of SayriteHide

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General Appearance of Type Material:
Yellow-orange to red-orange, prismatic crystals with maximum size 0.6 x 0.3 x 0.1 mm
Place of Conservation of Type Material:
Royal Museum of Central Africa, Tervaren, Belgium
Geological Setting of Type Material:
Uranium deposit
Associated Minerals at Type Locality:

Synonyms of SayriteHide

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Other Language Names for SayriteHide

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Dutch:Sayriet
German:Sayrit
Russian:Сэйрит
Spanish:Sayrita

Common AssociatesHide

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Associations Based on Photo Data:
5 photos of Sayrite associated with UraniniteUO2
4 photos of Sayrite associated with UranophaneCa(UO2)2(SiO3OH)2 · 5H2O
3 photos of Sayrite associated with Rutherfordine(UO2)CO3
2 photos of Sayrite associated with BecquereliteCa(UO2)6O4(OH)6 · 8H2O
2 photos of Sayrite associated with MasuyitePb(UO2)3O3(OH)2 · 3H2O

Related Minerals - Strunz-mindat GroupingHide

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4.GB.05RameauiteK2Ca(UO2)6O6(OH)4 · 6H2OMon. m : Bb
4.GB.05AgrinieriteK2(Ca,Sr)[(UO2)3O3(OH)2]2 · 5H2OMon. m : Bm
4.GB.05CompreignaciteK2(UO2)6O4(OH)6 · 7H2OOrth. mmm(2/m2/m2/m) : Pnnm
4.GB.10BecquereliteCa(UO2)6O4(OH)6 · 8H2OOrth. mm2 : Pna21
4.GB.10BillietiteBa(UO2)6O4(OH)6 · 4-8H2OOrth. mm2
4.GB.10ProtasiteBa(UO2)3O3(OH)2 · 3H2OMon. m
4.GB.15Richetite(Fe3+,Mg)Pb 8.6(UO2)36O36(OH)24 · 41H2O Tric. 1 : P1
4.GB.20Calciouranoite(Ca,Ba,Pb)U2O7 · 5H2O
4.GB.20BauranoiteBa(UO2)2(OH)6 · 1-2H2O
4.GB.20Metacalciouranoite(Ca,Ba,Pb,K2)U2O7 · 2H2O
4.GB.25FourmarieritePb(UO2)4O3(OH)4 · 4H2OOrth. mm2
4.GB.30WölsendorfitePb7(UO2)14O19(OH)4 · 12H2OOrth. mmm(2/m2/m2/m) : Cmcm
4.GB.35MasuyitePb(UO2)3O3(OH)2 · 3H2OOrth. mmm(2/m2/m2/m)
4.GB.40VandendriesscheitePbU7O22 · 12H2OOrth. mmm(2/m2/m2/m) : Pbca
4.GB.40MetavandendriesscheitePbU7O22 · nH2O n < 12Orth.
4.GB.45VandenbrandeiteCu(UO2)(OH)4Tric. 1 : P1
4.GB.55CuritePb3(H2O)2[(UO2)4O4(OH)3]2Orth. mmm(2/m2/m2/m) : Pnma
4.GB.60Iriginite(UO2)Mo2O7 · 3H2OOrth. mmm(2/m2/m2/m) : Pbcm
4.GB.65UranosphaeriteBi(UO2)O2(OH)Mon. 2/m
4.GB.70HolfertiteCaxU6+2-xTi(O8-xOH4x) · 3H2OTrig. 3 : P3
4.GB.75Carlosbarbosaite(UO2)2Nb2O6(OH)2 · 2H2OOrth. mmm(2/m2/m2/m) : Cmcm
4.GB.80GauthieriteKPb[(UO2)7O5(OH)7] · 8H2OMon. 2/m : P21/b
4.GB.85KroupaiteKPb0.5[(UO2)8O4(OH)10] · 10H2OOrth. mmm(2/m2/m2/m) : Pbca
4.GB.90LeesiteK(H2O)2[(UO2)4O2(OH)5] · 3H2OOrth. mmm(2/m2/m2/m) : Pbca
4.GB.95ShinkolobweitePb1.333[U5+O(OH)(UO2)5O4.67(OH)5.33](H2O)5Orth. mmm(2/m2/m2/m) : Pnnm
4.GB.95NollmotziteMg[U5+(U6+O2)2O4F3] · 4H2OMon. m : Bm

RadioactivityHide

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Radioactivity:
Element % Content Activity (Bq/kg) Radiation Type
Uranium (U) 60.5175% 15,129,375 α, β, γ
Thorium (Th) 0.0000% 0 α, β, γ
Potassium (K) 0.0000% 0 β, γ

For comparison:

  • Banana: ~15 Bq per fruit
  • Granite: 1,000–3,000 Bq/kg
  • EU exemption limit: 10,000 Bq/kg

Note: Risk is shown relative to daily recommended maximum exposure to non-background radiation of 1000 µSv/year. Note that natural background radiation averages around 2400 µSv/year so in reality these risks are probably extremely overstated! With infrequent handling and safe storage natural radioactive minerals do not usually pose much risk.

Interactive Simulator:

Note: The mass selector refers to the mass of radioactive mineral present, not the full specimen, also be aware that the matrix may also be radioactive, possibly more radioactive than this mineral!

Activity:

DistanceDose rateRisk
1 cm
10 cm
1 m

The external dose rate (D) from a radioactive mineral is estimated by summing the gamma radiation contributions from its Uranium, Thorium, and Potassium content, disregarding daughter-product which may have a significant effect in some cases (eg 'pitchblende'). This involves multiplying the activity (A, in Bq) of each element by its specific gamma ray constant (Γ), which accounts for its unique gamma emissions. The total unshielded dose at 1 cm is then scaled by the square of the distance (r, in cm) and multiplied by a shielding factor (μshield). This calculation provides a 'worst-case' or 'maximum risk' estimate because it assumes the sample is a point source and entirely neglects any self-shielding where radiation is absorbed within the mineral itself, meaning actual doses will typically be lower. The resulting dose rate (D) is expressed in microsieverts per hour (μSv/h).

D = ((AU × ΓU) + (ATh × ΓTh) + (AK × ΓK)) / r2 × μshield

Other InformationHide

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Notes:
Radioactive
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for SayriteHide

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References for SayriteHide

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Localities for SayriteHide

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Showing 6 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the 👁 Image
symbol to view information about a locality. The 👁 Image
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Locality ListHide

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👁 Image
- This locality has map coordinates listed.
👁 Image
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. 👁 Image
- Good crystals or important locality for species.
👁 Image
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Brazil
  • Bahia
Pires et al. (2014)
DR Congo (TL)
  • Haut-Katanga
    • Kambove Territory
      • Shinkolobwe
propriétés et structure cristalline. Bulletin de Minéralogie (3) +2 other references
Egypt
  • South Sinai Governorate
    • Abu Zeneima (Abu Zenima)
Sallam (2020)
Finland
  • Lapland
    • Enontekiö
Al-Ani et al. (2011) +2 other references
    • Rovaniemi
Al Ani
  • North Ostrobothnia
    • Kuusamo
Al-Ani et al. (2011)
Quick NavTopAbout SayriteUnique IdentifiersSimilar NamesIMA Classification Classification Mineral SymbolsPronunciation Physical Properties Optical Data Chemistry Crystallography Crystal StructureX-Ray Powder DiffractionGeological EnvironmentType Occurrence SynonymsOther LanguagesCommon AssociatesStrunz-MindatRadioactivityOther InformationInternet Links References Localities Locality List
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